The sear on the pork chops is the most important step. A deeply golden crust on both sides produces the flavor that carries through the entire skillet. Do not rush it and do not move the chops during the sear.
Char the green beans before they go back into the skillet. Blistered, slightly charred green beans have a completely different, more interesting flavor than plain cooked ones.
Toast the orzo in the peach mixture for 2 to 3 minutes before the broth goes in. This adds a nutty depth to the orzo that makes the finished skillet taste more developed.
The hot honey at the end is not optional in spirit. The sweet heat drizzled over the peach and pork combination is the finishing detail that makes the dish extraordinary.